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- 2011
- 2012
- 2013
- Hydrogen Dynamics in Nanoconfined Lithium borohydride
- Nuclear magnetic resonance study of hydrogen dynamics in Y(BH4)3
- Controlling the Dehydrogenation Reaction toward Reversibility of the Eutectic System
- Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?
- Reversible hydrogen storage in Mg(BH4)2/carbon nanocomposites
- 2014
- 2015
Is Y2(B12H12)3 the main intermediate in the decomposition process of Y(BH4)3?
Dodecaborates, i.e. the [B12H12]2 containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)3, yttrium octahydrotriborate, i.e. Y(B3H8)3, rather than the stable Y2(B12H12)3, is formed as the main intermediate.